When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | CH3C(O)_Parkes(1981)_298K_225nm(recalc).txt |
NAME: | acetyl radical |
FORMULA: | CH3C(O) |
AUTHOR(YEAR): | Parkes(1981) |
T: | 298K |
λ: | 225nm(recalc) |
BIBLIOGRAPHY: |
D.A. Parkes, "The ultraviolet absorption spectra of the acetyl radical and the kinetics of the CH3 + CO reaction at room temperature",
Chem. Phys. Lett. 77, 527-532 (1981);
DOI: 10.1016/0009-2614(81)85201-3
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COMMENTS: | A value of σ (225 nm) = 1×10-17 cm2 molecule-1 was derived using the rate constant k5 [CH3CO + CH3CO → (CH2CO)2] = 3×10-11 cm3 molecule-1 s-1The lower value was derived by C. Anastasi and P.R. Maw, "Reaction kinetics in acetyl chemistry over a wide range of temperature", J. Chem. Soc. Faraday Trans. I 78, 2423-2433 (1982): DOI: 10.1039/F19827802423, using their result k5 = 1.3×10-11 cm3 molecule-1 s-1 |
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